Tetrahedron p. 14823 - 14828 (1999)
Update date:2022-08-11
Topics:
Snider, Barry B.
Shi, Bo
The first syntheses of the antitumor agents (E)-volkendousin (1) and acetonide 3 have been accomplished by efficient routes from readily available dehydroisoandrosterone (7) using allylic oxidation with SeO2 to introduce the 4β-hydroxy group and 16- ketone. This sequence should make these compounds readily available for further biological evaluation.
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