Tetrahedron p. 14829 - 14838 (1999)
Update date:2022-08-04
Topics:
Buckle, Ronald N.
Burnell, D. Jean
Diels-Alder reactions took place with modest diastereoselectivity between dimethylcyclohexadiene derivative 3a and di-(-)-menthyl acetylenedicarboxylate, whereas the dimethylcyclohexadiene 2 showed no selectivity whatsoever. These results can be rationalized in terms of a complete lack of any endo-exo preference for the carboxylate groups and a more synchronous addition with 3a than with 2.
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