Reactivity of an α-Acyl-α-cyclopropyl-carbenium Ion: a Highly Stereoselective Cyclopropylmethyl-Cyclopropylmethyl Rearrangement

DOI: 10.1039/c39820001037

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1037 - 1039 (1982)

Update date:2022-08-17

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Authors:

Pardo, Claude

Charpentier-Morize, Micheline

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Article abstract of DOI:10.1039/c39820001037

The complete stereoselectivity in a cyclopropylmethyl-cyclopropylmethyl rearrangement which has been investigated is rationalized in terms of a highly preferred conformation of the transient α-acyl-α-cyclopropyl-carbenium ion.

Full text of DOI:10.1039/c39820001037

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