Deamination of Axial and Equatorial trans-2-Decalylamines by the N-Nitrosoamide Method in Various Solvents. Remarkable Stereochemistry and Efficiency of Capture of a Cationic Intermediate by Acetonitrile

DOI: 10.1021/jo01302a019

Source and publish data:

Journal of Organic Chemistry p. 2847 - 2854 (1980)

Update date:2022-08-04

Topics:

Authors:

Cohen, Theodore

Daniewski, Andrej R.

Solash, Jeffrey

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01302a019

Product distributions have been determined for thermal decomposition of the axial ethyl N-(trans,trans-2-decalyl)-N-nitrosocarbamate (3) and the equatorial epimer (4) in cyclohexane, acetic acid, acetonitrile and sulfolane.In cyclohexane, the axial substr

Full text of DOI:10.1021/jo01302a019

Products guided by the article

Product name:ethyl N-nitroso-N-cyclohexylcarbamate

Cas No:6558-81-2

R&D Labs maybe for 6558-81-2

Shanghai Dianyang Industry Co.,ltd

Contact:+86 21 6492 4669

Address:Chejing RD, Songjiang District, Shanghai, China
CHINA MEHECO CORPORATION

Contact:+86-10-67147360/67107388

Address:No.18 Guangming Zhongjie, Chongwen District, Beijing, 100061, China
SuZhou Bichal Biological Technology CO.,LTD

Contact:+86-512-68051130

Address:NO.32 huoju road HI-TECH Industrial development zone SuZhou China
ZHIJIANG ZENVA SINO COMMERCE AND TRADE CO., LTD.

website:http://www.zenvasino.com

Contact:+86-138-72658998

Address:Shibeishan Road,Zhijiang, Hubei, China
Sichuan Sangao Biochemical Co., Ltd

Contact:+86-28-84874233

Address:19F, Bldg.2, Shudu Center, Tianfu 2nd St., Hi-tech zone, Chengdu 610041, Sichuan Province, China.

Relevant to this article

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

Doi:10.1021/ol503176y
(2014)
Doi:10.1021/ja00793a048
(1973)
First stereoselective total synthesis and reconfirmation of absolute structure of nonenolide (?)-stagonolide D

Doi:10.1016/j.tetlet.2016.12.042
(2017)
Tertiary phosphine binding to pyridylazole chelated rhenium via substitution in phosphine oxide precursors: Geometrical preference, twin isomerization and effects of diphosphine spacer length and metal oxidation state

Doi:10.1039/b307834e
(2003)
Regioselective mono and multiple alkylation of diols and polyols catalyzed by organotin and its applications on the synthesis of value-added carbohydrate intermediates

Doi:10.1016/j.tet.2016.04.076
(2016)
Functionalized-arene ruthenium half-sandwich compounds as enantioselective hydrogen transfer catalysts. Crystal structures of [RuCl{TsNCH(R)CH(R)NH₂}(η⁶-C₆H ₅OCH₂CH₂OH)] (R = H or Ph)

Doi:10.1016/S0020-1693(03)00151-8
(2003)

Article Doi