Deamination of Axial and Equatorial trans-2-Decalylamines by the N-Nitrosoamide Method in Various Solvents. Remarkable Stereochemistry and Efficiency of Capture of a Cationic Intermediate by Acetonitrile

DOI: 10.1021/jo01302a019

Source and publish data:

Journal of Organic Chemistry p. 2847 - 2854 (1980)

Update date:2022-08-04

Topics:

Authors:

Cohen, Theodore

Daniewski, Andrej R.

Solash, Jeffrey

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo01302a019

Product distributions have been determined for thermal decomposition of the axial ethyl N-(trans,trans-2-decalyl)-N-nitrosocarbamate (3) and the equatorial epimer (4) in cyclohexane, acetic acid, acetonitrile and sulfolane.In cyclohexane, the axial substr

Full text of DOI:10.1021/jo01302a019

Products guided by the article

Product name:ethyl N-nitroso-N-cyclohexylcarbamate

Cas No:6558-81-2

R&D Labs maybe for 6558-81-2

Xi'an Galaxy Chemicals CO., Ltd

Contact:86-29-89380370

Address:No.8, Gaoxin three road, Xi'an city.
SHANGHAI GILEADER ADVANCE MATERIAL TECHNOLOGY CO.,LTD

Contact:+86-021-58692556

Address:No.6 Building,No. 668 Hengan RD Pudong,Shanghai
Synchem Pharma Co.,Ltd(expird)

Contact:+0086-21-61984905-1

Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Buffett (China) Holding Co.,Ltd

Contact:4006570891

Address:
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073

Relevant to this article

Silver(I)-catalyzed ring-contractive rearrangement: A new entry to 5-alkylidene-2-cyclopentenones

Doi:10.1021/ol503176y
(2014)
Doi:10.1021/ja00793a048
(1973)
First stereoselective total synthesis and reconfirmation of absolute structure of nonenolide (?)-stagonolide D

Doi:10.1016/j.tetlet.2016.12.042
(2017)
Tertiary phosphine binding to pyridylazole chelated rhenium via substitution in phosphine oxide precursors: Geometrical preference, twin isomerization and effects of diphosphine spacer length and metal oxidation state

Doi:10.1039/b307834e
(2003)
Regioselective mono and multiple alkylation of diols and polyols catalyzed by organotin and its applications on the synthesis of value-added carbohydrate intermediates

Doi:10.1016/j.tet.2016.04.076
(2016)
Functionalized-arene ruthenium half-sandwich compounds as enantioselective hydrogen transfer catalysts. Crystal structures of [RuCl{TsNCH(R)CH(R)NH₂}(η⁶-C₆H ₅OCH₂CH₂OH)] (R = H or Ph)

Doi:10.1016/S0020-1693(03)00151-8
(2003)

Article Doi