Deamination of Axial and Equatorial trans-2-Decalylamines by the N-Nitrosoamide Method in Various Solvents. Remarkable Stereochemistry and Efficiency of Capture of a Cationic Intermediate by Acetonitrile

DOI: 10.1021/jo01302a019

Source and publish data:

Journal of Organic Chemistry p. 2847 - 2854 (1980)

Update date:2022-08-04

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Authors:

Cohen, Theodore

Daniewski, Andrej R.

Solash, Jeffrey

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Article abstract of DOI:10.1021/jo01302a019

Product distributions have been determined for thermal decomposition of the axial ethyl N-(trans,trans-2-decalyl)-N-nitrosocarbamate (3) and the equatorial epimer (4) in cyclohexane, acetic acid, acetonitrile and sulfolane.In cyclohexane, the axial substr

Full text of DOI:10.1021/jo01302a019

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