The rearrangements of α-imino-thioaldehydes into dihydro-1,3-thiazoles

DOI: 10.1016/S0040-4039(00)74414-5

Source and publish data:

Tetrahedron Letters p. 8389 - 8392 (1994)

Update date:2022-08-11

Topics:

Authors:

Arnaud Arnaud

Pelloux-Leon

Ripoll Ripoll

Vallee Vallee

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Article abstract of DOI:10.1016/S0040-4039(00)74414-5

α-Imino-thioaldehydes were generated by retro-Diels-Alder reaction under nash vacuum thermolysis conditions. They were found to be unstable and cyclized to 2,3-dihydro-1.3-thiazoles. This cyclization was investigated by ab initio calculations.

Full text of DOI:10.1016/S0040-4039(00)74414-5

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