Journal of the American Chemical Society p. 902 - 905 (2014)
Update date:2022-08-11
Topics:
Hau, Sam C. K.
Mak, Thomas C. W.
Two new silver(I) carbides, Ag2C6 and Ag 2C8, have been synthesized, and single-crystal X-ray analysis of their crystalline silver(I) trifluoroacetate complexes, Ag 2C6·8AgCF3CO2·6H 2O, 4(Ag2C6)·16AgCF3CO 2·14.5DMSO, and 2.5(Ag2C8) ·10AgCF3CO2·10DMSO, provides detailed information on the influence of ligand disposition and orientation of the all-carbon anionic ligands in the construction of multidimensional supramolecular structures, which are consolidated by argentophilic and weak inter-/intramolecular interactions.
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