THERMAL 1,5-REARRANGEMENT OF A SILYL GROUP FROM OXYGEN TO CARBON

DOI: 10.1016/S0040-4039(01)82953-1

Source and publish data:

Tetrahedron Letters p. 4347 - 4348 (1981)

Update date:2022-08-25

Topics:

Authors:

Anderson, Gerard

Cameron, Donald W.

Feutrill, Geoffrey I.

Read, Roger W.

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Article abstract of DOI:10.1016/S0040-4039(01)82953-1

Trialkylsilyl ethers of 1,1-dioxygenated butadienes, substituted at position 3 by electron releasing substituents, undergo thermal rearrangement with 1,5-migration of the silyl group from oxygen to carbon.

Full text of DOI:10.1016/S0040-4039(01)82953-1

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