Chemistry of Heterocyclic Compounds p. 1273 - 1276 (1983)
Update date:2022-08-11
Topics:
Pastushenko, E. V.
Kurbanov, D.
Zlotskii, S. S.
Rakhmankulov, D. L.
In the presence of tert-butyl peroxide, 2-dimethylamino-1,3-dioxacyclanes are converted to esters of dimethylcarbamic acid.The reaction is described by a kinetic equation for an unbranched chain reaction with quadratic chain termination.The five-membered heterocycle is more reactive than the six-membered heterocycle.The predominant site for free radical attack is the methine group adjacent to the three heteroatoms.
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