Journal of the Chemical Society. Chemical communications p. 1326 - 1328 (1982)
Update date:2022-08-10
Topics:
Yamamoto, Yoshinori
Saito, Yoshikazu
Maruyama, Kazuhiro
Regio- and stereo-selective coupling between trimethylsilyl allyl carbanions and aldehydes is achieved in the presence of an additive, 'M'; use of R2BCl or EtAlCl2 as the additive gives the threo isomer (3) predominantly, while use of Bu3SnCl-BF3 affords the erythro isomer exclusively.
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(1981)