Journal of Organic Chemistry p. 7913 - 7919 (2017)
Update date:2022-07-30
Topics:
Jiang, Tian
Gu, Zheng-Yang
Yin, Ling
Wang, Shun-Yi
Ji, Shun-Jun
A Co(II)-catalyzed isocyanide insertion reaction with sulfonyl azides in alcohols to form sulfonyl isoureas via nitrene intermediate has been developed. This protocol provides a new, environmentally friendly, and simple strategy for the synthesis of sulfonyl isourea derivatives by employing a range of substrates under mild conditions.
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