Synthesis and structure of P,N-heterodifunctional ferrocene ligands and their transition metal complexes for palladium-catalyzed aryl amination reaction

DOI: 10.1016/S0040-4039(97)01807-8

Source and publish data:

Tetrahedron Letters p. 7613 - 7616 (1997)

Update date:2022-08-22

Topics:

Authors:

Molina, Pedro

Arques, Antonio

Garcia, Alejandro

De Arellano, M. Carmen Ramirez

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Article abstract of DOI:10.1016/S0040-4039(97)01807-8

The Staudinger reaction of the β-ferrocenylvinylazide I with di- and triphosphines provided a new range of P,N-heterodifunctional ferrocene ligands bearing an iminophosphorane and at least a diphenylphosphino group; reactivity towards Pd (II) and the ability of the resulting complexes for palladium catalyzed aryl amination reaction is described.

Full text of DOI:10.1016/S0040-4039(97)01807-8

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