Kinetics and Mechanism of the Oxidation of Hypophospite with N-Chlorotoluene-p-sulphonamide (Chloramine T) catalysed by Osmium(VIII) in Alkaline Solution

DOI: 10.1039/DT9910000089

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 89 - 92 (1991)

Update date:2022-08-11

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Authors:

Hussain, Juzar

Mishra, Som Kant

Sharma, Preen Dutt

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Article abstract of DOI:10.1039/DT9910000089

The kinetics of osmium(VIII)-catalysed oxidation of hypophosphite, H2PO2^-, with chloramine T (cat, N-chlorotoluene-p-sulphamide) was studied by estimating the latter iodometrically.The rate law (i) holds for -> = 0.02-0.142, View More

Full text of DOI:10.1039/DT9910000089

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