Journal of Physical Chemistry p. 8274 - 8279 (1991)
Update date:2022-08-25
Topics:
Gord, James R.
Freiser, Ben S.
Buckner, Steven W.
Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) has been used to study the single charge-transfer reactions of V2+ and Ta2+ with benzene under thermal conditions.Thermal charge-transfer rate constants of 2.0 x 10-9 and 1.2 x 10-9 cm3 molecule-1s-1 were measured for V2+ and Ta2+, respectively.The total kinetic energy of the product ions was determined to be 1.91 +/- 0.50 eV for the V2+ case and 2.82 +/- 0.50 eV for the Ta2+ case.These results and a previous study of the Nb2+ - benzene single charge-transfer system suggest a simple long-distance electron-transfer mechanism proceeding by ionization of the 1a2u orbital of benzene with significant internal excitation of the nascent C6H6+ product.
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