CHEMILUMINESCENCE OF N-METHYL-9-(DICARBOALKOXYMETHYL)ACRIDANES: SUCCESSIVE FORMATION OF TWO 1,2-DIOXETANONE INTERMEDIATES

DOI: 10.1016/S0040-4039(00)88081-8

Source and publish data:

Tetrahedron Letters p. 3005 - 3008 (1983)

Update date:2022-08-11

Topics:

Authors:

Suzuki, Nobutaka

Tsukamoto, Toshio

Izawa, Yasuji

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Article abstract of DOI:10.1016/S0040-4039(00)88081-8

N-Methyl-9-(dicarboalkoxymethyl)acridanes (5a-c) which have a similar structural moiety to that of firefly luciferin and give an excellent fluorescent product were found to be chemiluminescent when being oxidized by molecular oxygen in DMSO in the presence of t-BuOK at 70 degC.

Full text of DOI:10.1016/S0040-4039(00)88081-8

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