Studies on the Photochemical Reactions of α,β-Acetylenic Ketones with Tetramethylethylene

DOI: 10.1021/ja00361a027

Source and publish data:

Journal of the American Chemical Society p. 6902 - 6907 (1983)

Update date:2022-08-17

Topics:

Authors:

Saba, Shahrokh

Wolff, Steven

Schroeder, Clemens

Margaretha, Paul

Agosta, William C.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00361a027

With exclusion of acid, photolysis of mixtures of 1 and 2 in benzene yields 7a and 8a, which rearrange readily to 3, the previously isolated product.Labeling experiments show that these dienes arise by intramolecular 1,4 transfer of hydrogen.Irradiation o

Full text of DOI:10.1021/ja00361a027

Products guided by the article

Product name:Hex-4-yn-3-one, 2,2-dimethyl-

Cas No:71932-99-5

R&D Labs maybe for 71932-99-5

Xi'an Costrong Pharmaceutical Co., Ltd.

Contact:029- 68576496

Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
SHANDONG ZHANHUA YONGHAO PHARMACEUTICAL TECH.CO.,LTD

Contact:+86-576-88685096

Address:GENGJU VILLAGE NORTH ONE KILOMETER,ZHANHUA DISTRICT,BINZHOU CITY,SHANDONG PROVINCE,CHINA.
SHANGHAI ARCADIA BIOTECHNOLOGY LTD.

Contact:+86-21-61353236

Address:SUITE 901, BUILDING WENSLI, 1378 LU JIA BANG RD, SHANGAHI 200011, P.R.CHINA
Shanghai Kefu Chemical Co.,Ltd.

Contact:+86-21-34616196

Address:Room601-602, Xuhui Business Building, No.168, Yude Road, Shanghai
Huangshan Violet Biological Technology Co., Ltd

Contact:+86-559-2335676

Address:16-201 JinShanYuan,JiangNan New City,TunXi District,HuangShan City,AnHui Province,China

Relevant to this article

Doi:10.1016/0095-8522(48)90022-1
(1948)
Structure and synthesis of 3,5-dimethyl-N-nitro-1H-pyrazole-1-carboxamidine

Doi:10.1134/S1070363215070087
(2015)
A concise synthesis of (+)-cerulenin from a chiral oxiranyllithium

Doi:10.1021/jo9618177
(1997)
Conjugate reduction of α,β-unsaturated ketones using an Mn(III) catalyst, phenylsilane and isopropyl alcohol

Doi:10.1016/S0040-4039(00)01728-7
(2000)
Oxidative addition of chlorohydrocarbons to a rhodium tris(pyrazolyl)borate complex

Doi:10.1021/acs.organomet.5b00131
(2015)
Crystal engineering construction of caffeic acid derivatives with potential applications in pharmaceuticals and degradable polymeric materials

Doi:10.1039/d0ce01403f
(2020)

Article Doi