Journal of Organic Chemistry p. 1889 - 1893 (1982)
Update date:2022-08-17
Topics:
Brower, K. R.
The molar activation volume for the reaction of coal with tetralin at 344 deg C is -27 +/-3 mL.This result suggests a transition state which is bimolecular and possibly ionic.It is inconsistent with hypothesis that the rate is controlled by homolysis of the coal molecule.The H/D kinetic isotope effect for the reaction of coal with tetralin containing deuterium at the α-positions is 2.1 +/-0.1 at 335 deg C.This result reinforces the conclusions based on the activation volume.
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