Preliminary communication. Silacyclopropanes from the reaction of silenes with Wittig reagents

DOI: 10.1016/0022-328X(88)89113-7

Source and publish data:

Journal of Organometallic Chemistry p. C9 - C12 (1988)

Update date:2022-08-11

Topics:

Authors:

Brook, A. G.

MacMillan, Andrew

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Article abstract of DOI:10.1016/0022-328X(88)89113-7

The stable silene (Me3Si)2Si=C(OSiMe3)Ad (Ad = adamantyl) was found to react with the phosphorous ylid Ph3P⁺CH2^- or its sulfur analog to form the related silacyclopropane, as shown by NMR spectroscopy and by derivatization with methanol or acetophenone.

Full text of DOI:10.1016/0022-328X(88)89113-7

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