Kinetics and Mechanisms of Nucleophilic Displacements with Heterocycles as Leaving Groups. 3. N-(Substituted benzyl)-2,4,6-triphenylpyridiniums: Effects of Benzyl Substitution on First- and Second-Order Rates

DOI: 10.1021/jo00332a014

Source and publish data:

Journal of Organic Chemistry p. 3831 - 3835 (1981)

Update date:2022-08-29

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Authors:

Katritzky, Alan R.

Musumarra, Giuseppe

Sakizadeh, Kumars

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Article abstract of DOI:10.1021/jo00332a014

1-(p-Methoxybenzyl)- and 1-(2-furfuryl)-2,4,6-triphenylpyridiniums react with piperidine in chlorobenzene by S_N1 and S_N2 mechanisms, the proportion of S_N1 increasing with temperature.Other 1-(substituted benzyl) derivative

Full text of DOI:10.1021/jo00332a014

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