Journal of the Chemical Society - Faraday Transactions p. 531 - 534 (1992)
Update date:2022-08-11
Topics:
Alexander, Anthony J.
Firth, Steven
Kroto, Harold W.
Walton, David R. M.
The microwave spectra of the title compounds, recorded in the 26.5-40.0 GHz region, are characteristic of symmetric top molecules, complicated by internal rotation and accompanied by vibrational satellites attributed to low-frequency skeletal bending modes.For Me3SiCCH, B0 = 1962.163 MHz and relative intensity measurements on the vibrational satellites give a value of 110 +/- 15 cm-1 for the degenerate Si-CC bending mode.Measurements on Me3SiCCD have been made, and the Si-C bond length has been determined as 1.83 +/- 0.01 Angstroem.For Me3SiCCCN, B0 = 711.8646MHz, whilst for Me3Si(CC)2CN, twenty broad-band symmetric-top transitions, from J = 41 to 60, have been observed and a B value of 331 +/- 2 MHz has been estimated.
View MoreContact:86-28-61993785
Address:No.70-13-21, North Section, Erhuan
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
website:http://www.fwdchem.com
Contact:86-21-54450828
Address:Room 802,Lotus Tower ,159 Tianzhou Road,Xuhui District,Shanghai
JIANGSU GRAND XINYI PHARMACEUTICAL CO.,LTD
website:http://www.xypharm.com/
Contact:+86-515-84383317
Address:Chenli Road,Costal Chemical Area Binhai,Yancheng, Jiangsu,China
Anhui Sunsing Chemicals Co.,Ltd
website:http://www.sunsingchem.com
Contact:0086-566-2023179
Address:Jin An industry park, Chizhou economic technical development zone, Anhui
Doi:10.1016/j.tetlet.2017.01.039
(2017)Doi:10.1002/cmdc.201800764
(2019)Doi:10.3762/bjoc.15.291
(2019)Doi:10.1039/d0ce00341g
(2020)Doi:10.1016/S0040-4039(98)80020-8
(1999)Doi:10.1021/jo00120a044
(1995)
