Journal of the Chemical Society. Perkin transactions II p. 717 - 720 (1983)
Update date:2022-08-02
Topics:
Jenkins, Terence C.
Perkins, M. John
E.s.r. spectroscopy has been used to determine the equilibrium constants for the hydrogen exchange reactions between N-t-butylhydroxamic acids and the stable piperidine N-oxyl (1); since the O-H bond strength in (1)-H is known, this gives an estimate of the O-H bond strengths in the hydroxamic acids.These are found to be stronger than those in dialkyl nitroxides and increase with increasing electron demand in the acyl group.
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