Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 179 - 184 (1988)
Update date:2022-08-11
Topics:
Imai, Yoshika
Aida, Koyo
Itaya, Kingo
The i.r. (4000-30 cm-1) and Raman (4000- 0 cm-1) spectra of trimethylselenonium iodide and dimethyl selenide have been obtained, together with those of their deuterated analogues.All the active fundamentals of the trimethylselenonium ion have been assigned, assuming C3v molecular symmetry.Normal coordinate calculations have been carried out for the trimethyl-selenonium ion and dimethyl selenide and the Se-C force constants of both the compounds are compared, including those of other corresponding chalcogenides.
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