Phenyl substitution effects on rate acceleration of cation radical deazetation of 2,3-diazabicyclo[2.2.2]oct-2-enes

DOI: 10.1016/0040-4039(96)00855-6

Source and publish data:

Tetrahedron Letters p. 4377 - 4380 (1996)

Update date:2022-08-11

Topics:

Authors:

Ikeda Ikeda

Minegishi

Takahashi

Miyashi Miyashi

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Article abstract of DOI:10.1016/0040-4039(96)00855-6

Under the 9,10-dicyanoanthracene (DCA)-photosensitized electron-transfer conditions 1-phenyl-2,3-diazabicyclo[2.2.2]oct-2-ene (1b) and 1,4-diphenyl- 2,3-diazabicyclo[2.2.2]oct-2-ene (1c) were deazetized with rate constants, k(-N2), of ca. 8.4 x 10^{7
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Full text of DOI:10.1016/0040-4039(96)00855-6

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