Journal of Physical Chemistry p. 3626 - 3630 (1991)
Update date:2022-08-30
Topics:
Seetula, Jorma A.
Gutman, David
The kinetics of the reactions of CH2I, CH2Br, CH2Cl, and CHCl2 with HI were studied in a tubular reactor coupled to a photoionization mass spectrometer.Rate constants were measured as a function of temperature (typically between 294 and 552 K) to determine Arrhenius parameters.For these and other R + HI reactions studied to date (i.e., those involving aklyl radicals), a linear free energy relationship was dicovered which correlates the large differences in reactivity among all these R + HI reactions with the inductive effect of the substitutent atoms or groups on the central carbon atom.
Shanghai agrotree chemical co.,ltd.
Contact:+86-21-50117563
Address:Room 8A,liangfeng building,No.8 dongfang RD.pudong,shanghai,China
suzhou chukai pharmateach co,.ltd
Contact:86-512-88812511
Address:Building 3, Wujiang Scientific Innovation Park, 2358 Changan Rd, Wujiang 215200, Jiangsu Province, P. R. China
Zhejiang Chemicals Import & Export Corporation
Contact:86-571-87043088
Address:No.37,Qingchun Road,Hangzhou,China
Fuxin Jintelai Fluorin Chemical Co., Ltd.
Contact:+86-0418-8229599
Address:, 7th Huagong Road, Fluorine industry development zone (Yimatu Town,Fumeng County),Fuxin City, Liaoning Province, China
VanderArk International Limited
Contact:86-10-82437576
Address:Qing He
Doi:10.1016/j.molstruc.2017.04.026
(2017)Doi:10.1039/cc9960002251
(1996)Doi:10.1021/jm050761i
(2006)Doi:10.1007/BF00963022
(1990)Doi:10.1039/c9ta10346e
(2020)Doi:10.1007/BF00771300
()
