SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED-METAL CARBIDO CLUSTER Fe5C(μ2-CO)3(CO)11(μ2-AuPEt3)-(μ4-AuPEt3) AND THE OXIDATION OF Fe-Au CLUSTERS

DOI: 10.1016/S0022-328X(00)83808-5

Source and publish data:

Journal of Organometallic Chemistry p. C73 - C78 (1982)

Update date:2022-08-11

Topics:

Authors:

Johnson, Brian F.G.

Kaner, David A.

Lewis, Jack

Rosales, Maria J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-328X(00)83808-5

Reaction of ^2- with excess (PEt3)AuCl/Tl(PF6) affords the mixed-metal cluster Fe5C(μ₂-CO)3(CO)11(μ₂-AuPEt3)(μ₄-AuPEt3) which has been shown by an X-ray structural analysis to exhibit a novel coordination for one of the AuPEt3 groups.This and another Fe-Au cluster, Fe4H(CO)12C(AuPEt3) undergo unusual oxidative rearrangements.

Full text of DOI:10.1016/S0022-328X(00)83808-5

Products guided by the article

Product name:Iron

Cas No:7439-89-6

R&D Labs maybe for 7439-89-6

LIAOYANG WANRONG CHEMICALS COMPANY LIMITED

Contact:86-419-2390789

Address:XINLI VILLAGE , DONG NINGWEI COUNTY,TAIZIHE DISTRICT, LIAOYANG , LIAONING
Sigma-Aldrich Chemie GmbH

website:http://www.sigmaaldrich.com

Contact:800 558-9160

Address:Industriestrasse 25CH-9471 Buchs SGSwitzerland
H&Y International Group Ltd

Contact:+86-571-86491666

Address:SHI XIANG ROAD
Shanghai Maxchemco Chemical Industry Co., Ltd.

Contact:(86)21-51079223

Address:No.1305-8, B241, the Ecust Park, Huajing Road, Xuhui District, Shanghai
Suzhou Tianma Specialty Chemicals Co.,Ltd

Contact:+86-512-68090577

Address:#199, Huayuan Rd, Mudu, Suzhou, Jiangsu, CHINA

Relevant to this article

Doi:10.1021/ja01587a023
(1956)
New purine derivatives for efficient preparation of nucleoside analogs via alkylation

Doi:10.1080/15257770008035027
(2000)
Synthesis and structural characterization of bisazocalix[4]arene with melamine: Metal ion extraction studies

Doi:10.1016/j.molliq.2014.12.020
(2015)
Bonding and molecular environment effects on near-infrared optical absorption behavior in nonlinear optical monoazo chromophore-polymer materials

Doi:10.1021/ma060033k
(2006)
ASYMMETRIC SYNTHESIS OF (+)-PHOSPHINOTHRICIN and (+)-2-AMINO-4-PHOSPHONOBUTYRIC ACID

Doi:10.1016/S0040-4039(01)91546-1
(1984)
Doi:10.1021/jo01058a041
(1962)

Article Doi