SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED-METAL CARBIDO CLUSTER Fe5C(μ2-CO)3(CO)11(μ2-AuPEt3)-(μ4-AuPEt3) AND THE OXIDATION OF Fe-Au CLUSTERS

DOI: 10.1016/S0022-328X(00)83808-5

Source and publish data:

Journal of Organometallic Chemistry p. C73 - C78 (1982)

Update date:2022-08-11

Topics:

Authors:

Johnson, Brian F.G.

Kaner, David A.

Lewis, Jack

Rosales, Maria J.

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Article abstract of DOI:10.1016/S0022-328X(00)83808-5

Reaction of ^2- with excess (PEt3)AuCl/Tl(PF6) affords the mixed-metal cluster Fe5C(μ₂-CO)3(CO)11(μ₂-AuPEt3)(μ₄-AuPEt3) which has been shown by an X-ray structural analysis to exhibit a novel coordination for one of the AuPEt3 groups.This and another Fe-Au cluster, Fe4H(CO)12C(AuPEt3) undergo unusual oxidative rearrangements.

Full text of DOI:10.1016/S0022-328X(00)83808-5

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