First Kinetic Measurements on SiD2: Absolute Rate Constant for the Reaction SiD2 + H2

DOI: 10.1039/ft9938904405

Source and publish data:

Journal of the Chemical Society - Faraday Transactions p. 4405 - 4406 (1993)

Update date:2022-08-16

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Authors:

Mason, Ben P.

Frey, H. Monty

Walsh, Robin

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Article abstract of DOI:10.1039/ft9938904405

SiD2, generated via the laser flash photolysis of phenyl<(2)H3>silane, has been detected via a ro-vibrational transition in its <*>(¹B₁)<--<*>(¹A₁) absorption band.It has been monitored for the first time in time-resolved studies to give an absolute rate constant of (3.8+/-0.2)E-12 cm³ molecule^-1 s^-1 for the reaction SiD2 + H2.Product SiH2 from this reaction was also observed.

Full text of DOI:10.1039/ft9938904405

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