Angewandte Chemie - International Edition p. 2546 - 2549 (2005)
Update date:2022-08-10
Topics:
Richards, Anne F.
Eichler, Barrett E.
Brynda, Marcin
Olmstead, Marilyn M.
Power, Philip P.
Tin can form examples of rare organically substituted clusters whose structures are related to Zintl salts. The two new types of metal-rich organotin clusters, a neutral Sn9Ar3 (see picture) and two ionic [Sn10Ar′3]+ species, were structurally characterized and their bonding situation investigated by density functional calculations. (Figure Presented).
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