RSC Advances p. 86172 - 86178 (2015)
Update date:2022-08-28
Topics:
Xu, Na
Zhu, Mingyuan
Zhang, Jinli
Zhang, Haiyang
Dai, Bin
To improve the activity and stability of Ru-based catalysts with a carbon support for acetylene hydrochlorination, activated carbon (AC) was consecutively modified by nitration, amination and pyridine, and the effect of the different carbon supports on the Ru-based catalysts for acetylene hydrochlorination was investigated. The results of the FT-IR studies confirmed that -NO2, -NH2 and -N-H-N groups were separately grafted onto the surface of the AC. Under the same reaction conditions, the modified catalysts exhibited better catalytic activity compared with the original Ru/AC catalyst. Moreover, the catalyst Ru/AC-NHN showed the best catalytic performance with a slight decrease after 48 h from 93.2% to 91.8%. The increase in catalytic activity indicates that the modification with nitrogen functional groups is beneficial for acetylene hydrochlorination.
View MoreTianjin Derchemist Sci-Tech Co., Ltd.
website:http://www.derchemist.com
Contact:+86-22-58627059
Address:Xinmao Science and Technology Park,Huayuan Industrial Park
HANGZHOU TOYOND BIOTECH CO., LTD
Contact:+86-571-86965177
Address:No. 189, Fengqi East Road, Hangzhou, China
Tianjin Dongchang Fine Chemical Industry Co., Ltd.
Contact:+86-22-29894595
Address:Economic Developing Zone, Ji County, Tianjin, China
Jiande City Silibase Silicone New Material Manufacture Co., Ltd.
Contact:15967177856
Address:Genglou Industrial Development Area
Suzhou Sinosun Imp.&Exp. Corporation
website:http://www.szsinosun.com
Contact:+86-512-63488895,63488616
Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Doi:10.1021/ja00317a014
(1984)Doi:10.1021/acs.joc.0c00996
(2020)Doi:10.1016/j.tetasy.2004.06.032
(2004)Doi:10.1103/PhysRevB.71.035119
(2005)Doi:10.1016/0040-4020(77)80403-1
(1977)Doi:10.1039/c6ta01319h
(2016)