Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2035 - 2046 (1987)
Update date:2022-08-11
Topics:
Grant, Robert B.
Harbach, Christopher A. J.
Lambert, Richard M.
Tan, S. Aun
Ethylene oxidation over well characterised Ag(111) surfaces has been investigated by temperature-programmed reaction measurements and by differential batch reactor studies at pressures up to 50 Torr.The influence of chlorine predosing on catalytic activity indicates that a chemisorbed atomic oxygen species is responsible for both partial oxidation and complete oxidation to CO2 + H2O.This tends to be confirmed by experiments using N2O as the oxidant, both with the single crystal specimen and with a practical Ag-αAl2O3 catalyst in a flow microreactor.Dissolved oxygen, like adsorbed chlorine, is found to be a selectivity promoter.Adsorbed Cs also increases the rate of ethylene oxide production but can also positively influence the overall activity of the system.The results suggest that chlorine and dissloved oxygen promoters principally affect the primary chemistry, whereas the main effect of Cs is on the secondary chemistry (further oxidation of ethylene oxide).This view tends to be confirmed by temperature-programmed reaction measurements and by direct experiments on the influence of Cl and Cs on the isomerisation and combustion of ethylene oxide itself.It is suggested that these effects are primarily electronic in origin and a mechanism based on this view is presented.In the presence of Cs, both CO2 and NOx can act as selectivity promoters for the formation of ethylene oxide.
View Moreshijiazhuang baisheng chem co.; ltd
Contact:86-0311-80790826
Address:shijiazhuang hebei
Wuhan Kemi-Works Chemical Co., Ltd
website:http://www.kemiworks.com
Contact:86-27-85736489
Address:Rm. 1503, No. 164, Jianghan North Rd., Wuhan, 430022 China
Contact:+86-25-85281586
Address:13F,Bld2#,South of Longpan Road
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.
Contact:+86-186-02659358
Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Contact:+(852) 301-98033
Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
Doi:10.1039/PS9600000193
(1960)Doi:10.1016/j.jmmm.2011.12.012
(2012)Doi:10.1139/v55-219
(1955)Doi:10.1007/BF00920728
()Doi:10.1016/S0040-4039(02)00231-9
(2002)Doi:10.1080/15533170600777903
()
