Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 2114 - 2123 (1980)
Update date:2022-08-23
Topics:
Adams, Paul A.
Sheppard, John G.
Precise first-order rate constants for the solvolysis of tert-butyl and tert-pentyl chlorides have been determined in water at temperatures up to 50 deg C for butyl chloride and 41 deg C for pentyl chloride.The results have been compared with previously published data on the hydrolysis of the two chlorides at lower temperatures, and, on detailed analysis, the results have provided a reliable picture of the temperature variation of the specific heat of activation (ΔCp) for these hydrolyses.
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