Journal of Physical Chemistry p. 3167 - 3169 (1989)
Update date:2022-08-29
Topics:
Zitter, R. N.
Koster, D. F.
Choudhury, T. K.
The decomposition of CF3Cl by a CW CO2 laser has been studied over a range of temperatures, 1280-1740 K, and Arrhenius plots show two distinct regimes.At lower temperatures, C2F6 is produced with an activation energy of 86.0 kcal/mol.At high temperatures, C2F6 production is characterized by an activation energy of 54.0 kcal/mol, and now CF4 and CF2Cl2 are detected, being produced at equal rates with an activatuion energy of 86.2 kcal/mol.A reaction mechanism in agreement with these results is presented, and we obtain hitherto unreported activation energy values for the radical-molecule reactions of CF3 and CF2Cl with CF3Cl.
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