Journal of Fluorine Chemistry p. 333 - 350 (1986)
Update date:2022-08-11
Topics:
Brower, K. R.
Combinations of liquid ClF3 with several hydrocarbons and halocarbons have been caused to explode by sudden mixing at various temperatures from 25 degC downward.The mixtures occasionally detonate.By fast recording of pressure, flame ionization, and carbon deposition it is found that mixtures derived from all of the fuels tested except perfluorohexane initiate in less than 1 ms at all temperatures down -70 degC.An ionic mechanism is proposed.Analysis of the explosion gases indicates that all chemical bonds including C-H are labilized owing to the extremely high temperature.Calorimetric measurements agree with calculated heats of explosion.
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