Journal of Organometallic Chemistry p. 291 - 296 (1983)
Update date:2022-08-16
Topics:
Gambaro, Alessandro
Peruzzo, Valerio
Marton, Daniele
Allylchlorotins of the type R(3-n)AllSnCln (R = alkyl or All; All = CH2=CHCH2 or cis/trans-CH3CH=CHCH2, n = 1-3) undergo uncatalyzed coupling with acyl chlorides under mild conditions.This reaction as well as the corresponding addition reaction to ketones are much faster when Cl is replaced by NCS group in the organotin derivative.
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