Synthesis and X-ray Structure of the Nickelabenzocyclopentene Complex . Reactivity Toward Simple, Unsaturated Molecules and the Crystal and Molecular Structure of the Cyclic Carboxylate <formula)

DOI: 10.1021/ja00190a023

Source and publish data:

Journal of the American Chemical Society p. 2883 - 2891 (1989)

Update date:2022-09-26

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Authors:

Carmona, Ernesto

Gutierrez-Puebla, Enrique

Marin, Jose M.

Monge, Angeles

Paneque, Margarita

at al. at al.

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Article abstract of DOI:10.1021/ja00190a023

Facile cyclometalation to the nickelacyclopentene complex (1) occurs upon alkylation of NiCl2(PMe3)2 with 2 equiv of Mg(CH2CMe2Ph)Cl, in the presence of traces I(1-).Compound 1 has been fully characterized by spectroscopic and X-ray studies.Its

Full text of DOI:10.1021/ja00190a023

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