Journal of Fluorine Chemistry p. 467 - 476 (1984)
Update date:2022-08-11
Topics:
Shack, Carl J.
Christe, Karl O.
Both pentafluorotellurium hypochlorite, TeF5OCl, and hypofluorite, TeF5OF, react with fluoroolefins to form TeF5O- containing fluorocarbons, a new class of compounds.In the case of TeF5OF, yields of the adducts are high (60-86percent) but are lower (22-30percent) with TeF5OCl.In the latter case extensive chlorofluorination of the olefin occurs.Olefins studied include CF2=CF2, CF3CF=CF2, CF2=CFCl, and perfluorocyclopentene.Details of the synthesis and characterization of these new fluorocarbons are presented.
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