Journal of the Chemical Society. Chemical communications p. 1035 - 1036 (1980)
Update date:2022-08-16
Topics:
Hebert, Eric
Welvart, Zoltan
The <1,2>- and <1,6>-rearrangements of s-octyl benzhydryl ether gave products in equal amounts whose formation occured with 20percent retention of configuration, and with complete racemization, for the <1,2>- and the <1,6>-products respectively; these results can be rationalized either by the formation of different non-equilibrating singlet radical pair intermediates, or by an important product formation after diffusion of the intermediate radical pairs.
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