Journal of the Chemical Society. Chemical communications p. 991 - 992 (1995)
Update date:2022-08-17
Topics:
Vidal, Veronique
Theolier, Albert
Thivolle-Cazat, Jean
Basset, Jean-Marie
Silica-supported tantalum hydride activates at low temperature the C-H and the C-D bonds of cyclooctane and CD4, respectively, to form the corresponding cyclooctyl and perdeuteriomethyl-tantalum surface complexes; these complexes are transformed under molecular oxygen into the corresponding tantalum-alkoxy derivatives which with acetic acid give rise to the corresponding alkylacetates.
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