Polar trifluoromethylation reactions. Synthesis and NMR spectra of tris(trifluoromethyl)antimony, Sb(CF3)3

DOI: 10.1016/0022-328X(87)85151-3

Source and publish data:

Journal of Organometallic Chemistry p. 193 - 198 (1987)

Update date:2022-08-16

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Authors:

Naumann, Dieter

Tyrra, Wieland

Leifeld, Ferdinand

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Article abstract of DOI:10.1016/0022-328X(87)85151-3

Bis(trifluoromethyl)cadmium complexes react with antimony trihalides in polar solvents to form Sb(CF3)3 in high yield.The reactions proceed stepwise and the mono- and bis(trifluoromethyl)antimony compounds formed as intermediates have been identified from

Full text of DOI:10.1016/0022-328X(87)85151-3

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