D2O product angular and translational energy distributions from the oxidation of deuterium on Pt(111)

Article abstract of DOI:10.1063/1.444646

The angular and translational energy distributions of D2O produced from the oxidation of deuterium on the (111) crystal face of platinum have been measured over the surface temperature range of 440-913 K.Although the angular distributions are described by a cosine function, the translational energy distributions deviate from the corresponding Maxwell-Boltzmann distributions.At the normal angle, the D2O mean translational energy /2k varies from 220 to 400 K over the temperature range investigated.Two mechanisms for the production of translationally cold product molecules are discussed.

Full text of DOI:10.1063/1.444646

D2O product angular and translational energy distributions from the oxidation of
deuterium on Pt(111)
S. T. Ceyer, W. L. Guthrie, T.H. Lin, and G. A. Somorjai
Citation: The Journal of Chemical Physics 78, 6982 (1983); doi: 10.1063/1.444646
View online: http://dx.doi.org/10.1063/1.444646
View Table of Contents: http://scitation.aip.org/content/aip/journal/jcp/78/11?ver=pdfcov
Published by the AIP Publishing
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This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30

This article is copyrighted as indicated in the article. Reuse of AIP content is subject to the terms at: http://scitation.aip.org/termsconditions. Downloaded to IP:
129.105.215.146 On: Fri, 19 Dec 2014 03:43:30