PHOTOLYTIC REARRANGEMENT OF PHOSPHORUS AZIDE : EVIDENCE FOR A TRANSIENT METAPHOSPHONIMIDATE.

DOI: 10.1016/S0040-4039(00)71119-1

Source and publish data:

Tetrahedron Letters p. 5015 - 5018 (1980)

Update date:2022-08-16

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Authors:

Bertrand, Guy

Majoral, Jean-Pierre

Baceiredo, Antoine

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Article abstract of DOI:10.1016/S0040-4039(00)71119-1

Photolysis of the oxide of diphenylphosphine azide gives rise to a transient metaphisphonimidate, a new tricoordinated pentavalent phosphorus compound.Evidence for this species was given by trapping reactions on a variety of substrates.

Full text of DOI:10.1016/S0040-4039(00)71119-1

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