Journal of the Chemical Society, Dalton Transactions p. 1415 - 1429 (1981)
Update date:2022-08-31
Topics:
Boocock, Simon K.
Greenwood, Norman N.
Hails, Michael J.
Kennedy, John D.
McDonald, Walter S.
The reaction of cis-a = 1.9771(8), b = 1.3025(4), c = 1.9773(4) nm, β = 110.99(3) deg, Z = 8, and the molecular structure is that of a nine-vertex arachno-platinanonaborane in which the B8 unit shows trihaptobonding to the metal centre.The compound is also formed in lower yield from several other polyhedral borane derivatives.The 14-vertex bis(dimethylphenylphosphine)bis-μ-(2-4-η-nido-hexaboranyl)-diplatinum(Pt-Pt), a = 1.3762(3), b = 1.5105(4), c = 1.9210(3) nm, β = 92.59(2) deg, and Z = 4; the molecular structure is that of an arachno-diplatina-decaborane anion a number of important structural correlations emerge.
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