Journal of the Chemical Society. Chemical communications p. 862 - 863 (1983)
Update date:2022-08-11
Topics:
Yoshifuji, Masaaki
Shibayama, Katsuhiro
Inamoto, Naoki
Hirotsu, Ken
Higuchi, Taiichi
The diphosphene ArP=PAr (Ar = 2,4,6-But3C6H2) reacts with elemental sulphur to give the stable monosulphide ArP(S)=PAr (2) whose structure was confirmed by an X-ray analysis; when treated with hexamethylphosphorous triamide, (2) reverts to the starting diphosphene but thermal and photochemical isomerisation of (2) gives the thiadiphosphirane Ar-cyclo
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