The reaction of Wittig-Horner reagents and phosphacumulenes with nitrosonaphthol

Article abstract of DOI:10.1080/10426509708043494

Wittig-Horner reagent 1a reacts with 2-nitroso-1-naphthol 3 to give the olefinic adduct 5, the alkylated product 4 and the dimeric compound 6. When 2-nitroso-1-naphthol 3 reacts with Wittig-Horner reagents 1b,c, the corresponding phosphonate adducts 8a,b together with compounds 4 and 6 were obtained. Oxovinylidenetriphenylphosphorane 2 reacts with 3 to give the corresponding phosphoranylidenecyclobutylidene adduct 10 and triphenylphosphine oxide. The structural assignments of the new products are based on compatible analytical and spectroscopic results.

Full text of DOI:10.1080/10426509708043494

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Phosphorus, Sulfur, and Silicon and
the Related Elements
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THE REACTION OF WITTIG-
HORNER REAGENTS AND
PHOSPHACUMULENES WITH
NITROSONAPHTHOL
a
a
a
L. S. Boulos , M. H.N. Arsanious & N. Khir El-din
a
National Research Centre , Dokki, Cairo, Egypt
Published online: 04 Oct 2006.
To cite this article: L. S. Boulos , M. H.N. Arsanious & N. Khir El-din (1997) THE REACTION OF
WITTIG-HORNER REAGENTS AND PHOSPHACUMULENES WITH NITROSONAPHTHOL, Phosphorus,
Sulfur, and Silicon and the Related Elements, 122:1, 49-58, DOI: 10.1080/10426509708043494
To link to this article: http://dx.doi.org/10.1080/10426509708043494
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