Tetrahedron p. 9781 - 9788 (1994)
Update date:2022-08-16
Topics:
Matsumoto, Takatoshi
Matsunaga, Nobuyuki
Kanai, Ayako
Aoyama, Toyohiko
Shioiri, Takayuki
Osawa, Eiji
Epimerization of tilivalline (1) at the C11-position occurred by treatment with zinc chloride to give a mixture of 1 and its 11-epimer (epi-1) in a ratio 83 : 17.The computational chemical analysis of the thermodynamic stability of 1 and epi-1 through MM3(92) also revealed the energetic preference of 1 and the calculated equilibrium ratio of 1 and epi-1 was consistent with the experimental results.The torsional and bending angle parameters around the amide bond were determined.
View More
Wuhan Shangrisyn chemicals Technology Co.,Ltd(expird)
Contact:+86-027-84466317 __ +86-15387123698
Address:wuhan - china
Jinan Jianfeng Chemical Co., Ltd
Contact:0086-531-88110457
Address:sales01(-a-t-)pharmachemm{dot}c+o+m
Zhejiang Newfine Industry Co.,Ltd.
Contact:+86-573-82262042
Address:No.225,Dongqing Road, garoms@163.com
Nanjing Chemzam Pharmtech Co., Ltd.
Contact:+86-25-86462165,+86-13915979898
Address:C5-1，6 Maiyue Road，Maigaoqiao，Nanjing，Jiangsu，China
Shenyang Xingzhenghe Chemical Co., Ltd.
Contact:024-23509232
Address:No. 33, Naner Road, Heping Dist.
Doi:10.1002/adsc.200505227
(2006)Doi:10.1016/j.bmcl.2016.09.017
(2016)Doi:10.1016/S0031-9422(96)00702-9
(1997)Doi:10.1016/j.jorganchem.2014.10.013
(2014)Doi:10.1021/ja3106253
(2013)Doi:10.1021/ja044760b
(2005)
