
Journal of the Chemical Society. Chemical communications p. 393 - 394 (1982)
Update date:2022-08-11
Topics:
Cloke, F. Geoffrey N.
Cox, Kevin P.
Green, Malcolm L. H.
Bashkin, Jim
Prout, Keith
Co-condensation of molybdenum atoms with an excess of trimethylphosphine gives hexakis(trimethylphosphine)molybdenum which crystal structure studies show to have an octahedral MoP6 unit; it is highly reactive to substitution by dinitrogen, olefins, and dihydrogen, forming a variety of derivatives.
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