Tetrahedron Letters p. 1989 - 1992 (1982)
Update date:2022-08-16
Topics:
Hassner, Alfred
Chau, William
D-Labelling permits differentiation between three plausible mechanistic pathways in the novel transformation of vinylaziridene 1 with β-nitrostyrene 4 to nitro enamino olefin 5.The results are consistent with a retro-ene reaction proceeding under mild conditions (80 deg C).Choice of proper substituents can guide the reaction toward formation of azepines or substituted enamines.
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(1983)
