Magnetic Resonance in Chemistry p. 130 - 133 (1989)
Update date:2022-08-10
Topics:
Jezierski, Adam
Reactions of silver(II) complexes with ketoxime, nitroso and isonitroso compounds in organic solvents were investigated by ESR.The oxidation yielded iminoxy radicals RR'C=NO. and/or nitroxides R1R2NO..The silver(II) complexes with nitrogen ligands (mono-, bi- and tri-dentate) and AgO were used as oxidizing agents.The reaction products were analysed on the basis of the ESR spectra.The signs of the 14N hyperfine constants for the radicals were determined using the ESR spectra in an MBBA liquid nematic crystal as solvent.A linear correlation was found between the hyperfine 14N parameters and the Dimroth-Reichardt ET(30) coefficients for the iminoxy radicals.KEY WORDS ESR Iminoxy radicals Nitroxides Silver(II)complexes
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