GROUP VIA METAL PENTACARBONYL COMPLEXES OF 2- AND 4-VINYLPYRIDINE AND THEIR COPOLYMERS. PREPARATION, SPECTROSCOPIC CHARACTERISATION AND PHOTOCHEMICAL PROPERTIES

Article abstract of DOI:10.1016/S0022-328X(00)96085-6

M(CO)5(4-VP) (M = Cr, Mo, or W) and M(CO)5(2-VP) (M = Cr, W), prepared from the reaction of M(CO)5(EtOH) and 2-vinylpyridine (2-VP) or 4-vinylpyridine (4-VP), have been characterised by IR, 1H NMR, and UV/visible absorption spectroscopy.Copolymers of M(CO