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Monocyclic β-Lactam Tripeptide, 1-(D-Carboxy-2-methylpropyl)-3-L-(δ-L-2-aminoadipamido)-4-L-mercaptoazetidin-2-one, a Putative Intermediate in Penicillin Biosynthesis

DOI: 10.1039/c39820001130

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1130 - 1132 (1982)

Update date:2022-08-11

Topics:

Authors:

Abraham, Edward P.Abraham, Edward P.

Adlington, Robert M.Adlington, Robert M.

Baldwin, Jack E.Baldwin, Jack E.

Crimmin, Michael J.Crimmin, Michael J.

Field, Leslie D.Field, Leslie D.

et al.et al.

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Article abstract of DOI:10.1039/c39820001130

The disulphide corresponding to the above thiol has been synthesised, but all attempts to reduce this substance to the thiol have been unsuccessful, although an alternative procedure, via a thiomercury intermediate, enabled the thiol to be generated in situ; the properties of this thiol, however, are not in accord with those described for a putative intermediate in penicillin biosynthesis.

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Product name:di-(4-nitrobenzyl (2S)-5-((2R, 3R)-2-mercapto-1-<(1R)-2-methyl-1-(4-nitrobenzyloxycarbonyl)propyl>-4-oxoazetidin-3-ylcarbamoyl)-2-(4-nitrobenzyloxycarbonylamino)pentanoate)disulphide

Cas No:84701-30-4

84701-30-4

R&D Labs maybe for 84701-30-4

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