Stability, Electronic Spectra, and Structure of Transition-metal Ion Complexes of a Novel Mixed-donor (Nitrogen-Sulphur) Macrocycle, 1-Thia-4,7-diazacyclononane

DOI: 10.1039/DT9830001601

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1601 - 1606 (1983)

Update date:2022-08-10

Topics:

Authors:

Hart, Susan M.

Boeyens, Jan C.A.

Michael, Joseph P.

Hancock, Robert D.

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Article abstract of DOI:10.1039/DT9830001601

The synthesis of the novel ligand 1-thia-4,7-diazacyclononane (L¹) is described.A potentiometric study yields pK₁ as 9.67, and pK₂ as 3.98 in 0.1 mol dm^-3 NaNO₃ at 25 deg C; complex-formation constant

Full text of DOI:10.1039/DT9830001601

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