Catalysis science and technology p. 1921 - 1927 (2017)
Update date:2022-08-11
Topics:
Fabre, Indira
Poisson, Thomas
Pannecoucke, Xavier
Gillaizeau, Isabelle
Ciofini, Ilaria
Grimaud, Laurence
We report the first copper-catalyzed olefinic ethoxy carbonyl difluoromethylation of alkenyl thioethers via direct C-H bond functionalization using BrCF2COOEt. The developed methodology allows the preparation of trisubstituted olefins with a controlled stereochemistry. A mechanistic study is reported and a radical mechanism is revealed.
Changzhou Kingyo Chemical Corporation Ltd.
website:http://www.kingyochem.com
Contact:+86-519-85105717
Address:19# Wuqing North Road, Changzhou , Jiangsu, China
Contact:
Address:
ShangHai Soyoung Biotechnology Inc
website:http://www.soyoungbio.com
Contact:+86-21-69893009
Address:shanghai
website:https://www.yacoo.com.cn/en/
Contact:86-512-87182055
Address:No.112 Xinqing Rd, Suzhou Industrial Park, China, 215125, China
Haitong Chemical Industrial Co.,Ltd.
website:https://www.haitonglongwin.com/
Contact:+86-022-66221018
Address:18-701, No.99, The 4th Street, TEDA,
Doi:10.1021/ol402717b
(2013)Doi:10.1016/0022-5088(69)90166-0
(1969)Doi:10.1002/ardp.19903230512
(1990)Doi:10.1002/1521-3773(20011203)40:23<4498::AID-ANIE4498>3.0.CO;2-3
(2001)Doi:10.1016/S0040-4039(98)00890-9
(1998)Doi:10.3390/molecules24244559
(2019)
